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I hope it isn't that. :(

Goat are actually quite delicate creatures and don't do well with pain or illness. They also have very sensitive digestive systems. So sorry you lost her sister.

If it's the scurs being knocked off, which can happen quite often, the horns are directly linked to the nasal passages. I've had it happen here a time or two. It heals after a bit and can be a bit painful, but I've never had anything else come of it.

Goats have a scent gland in that area. Might have something to do with that. Otherwise it could be wound. I probably would use bluekote, and do a week or two of penicillin, but hopefully you can get a hold of the vet.