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It's advised to spray plants with neem in the evening so that you aren't at risk of spraying pollinators. Directly spraying them will kill them, but any spray residue on the plant at the recommended dosage won't hurt them. http://www.discoverneem.com/neem-bees-beneficial-insects.html

Pure neem oil degrades quickly in the sunlight or rain so I doubt there will be any left on the greens by the time your chickens actually eat it. Interestingly, I know finch breeders will brew up neem leaf tea as a medicine and to treat air sac mites.

Yes, neem is non toxic to birds. I've used it in the coop to get rid of red mites. Just be careful when you spray it so that bees are not affected.